ENTRY R07775 Reaction NAME S-adenosyl-L-methionine:cobalt-precorrin-7 C5-methyltransferase DEFINITION Cobalt-precorrin 7 + S-Adenosyl-L-methionine <=> Cobalt-precorrin 8 + S-Adenosyl-L-homocysteine EQUATION C16244 + C00019 <=> C11545 + C00021 RCLASS RC00003 C00019_C00021 RC02053 C11545_C16244 ENZYME 2.1.1.289 PATHWAY rn00860 Porphyrin metabolism rn01100 Metabolic pathways rn01240 Biosynthesis of cofactors MODULE M00924 Cobalamin biosynthesis, anaerobic, uroporphyrinogen III => sirohydrochlorin => cobyrinate a,c-diamide BRITE Enzymatic reactions [BR:br08201] 2. Transferase reactions 2.1 Transferring one-carbon groups 2.1.1 Methyltransferases 2.1.1.289 R07775 Cobalt-precorrin 7 + S-Adenosyl-L-methionine <=> Cobalt-precorrin 8 + S-Adenosyl-L-homocysteine ORTHOLOGY K00595 precorrin-6B C5,15-methyltransferase / cobalt-precorrin-6B C5,C15-methyltransferase [EC:2.1.1.132 2.1.1.289 2.1.1.196] K03399 cobalt-precorrin-7 (C5)-methyltransferase [EC:2.1.1.289] DBLINKS RHEA: 34594 /// ENTRY R07772 Reaction NAME cobalt-precorrin 5A acylhydrolase DEFINITION Cobalt-precorrin 5A + H2O <=> Cobalt-precorrin 5B + Acetaldehyde EQUATION C16242 + C00001 <=> C16243 + C00084 RCLASS RC01545 C00084_C16242 RC02097 C16242_C16243 ENZYME 3.7.1.12 PATHWAY rn00860 Porphyrin metabolism rn01100 Metabolic pathways rn01240 Biosynthesis of cofactors MODULE M00924 Cobalamin biosynthesis, anaerobic, uroporphyrinogen III => sirohydrochlorin => cobyrinate a,c-diamide BRITE Enzymatic reactions [BR:br08201] 3. Hydrolase reactions 3.7 Acting on carbon-carbon bonds 3.7.1 In ketonic substances 3.7.1.12 R07772 Cobalt-precorrin 5A + H2O <=> Cobalt-precorrin 5B + Acetaldehyde ORTHOLOGY K02189 cobalt-precorrin 5A hydrolase [EC:3.7.1.12] K13541 cobalt-precorrin 5A hydrolase / cobalt-factor III methyltransferase / precorrin-3B C17-methyltransferase [EC:3.7.1.12 2.1.1.272 2.1.1.131] DBLINKS RHEA: 26284 /// ENTRY R07773 Reaction NAME S-adenosyl-L-methionine:cobalt-precorrin-5B (C1)-methyltransferase DEFINITION Cobalt-precorrin 5B + S-Adenosyl-L-methionine <=> Cobalt-precorrin 6 + S-Adenosyl-L-homocysteine EQUATION C16243 + C00019 <=> C11542 + C00021 RCLASS RC00003 C00019_C00021 RC02051 C11542_C16243 ENZYME 2.1.1.195 PATHWAY rn00860 Porphyrin metabolism rn01100 Metabolic pathways rn01240 Biosynthesis of cofactors MODULE M00924 Cobalamin biosynthesis, anaerobic, uroporphyrinogen III => sirohydrochlorin => cobyrinate a,c-diamide BRITE Enzymatic reactions [BR:br08201] 2. Transferase reactions 2.1 Transferring one-carbon groups 2.1.1 Methyltransferases 2.1.1.195 R07773 Cobalt-precorrin 5B + S-Adenosyl-L-methionine <=> Cobalt-precorrin 6 + S-Adenosyl-L-homocysteine ORTHOLOGY K02188 cobalt-precorrin-5B (C1)-methyltransferase [EC:2.1.1.195] DBLINKS RHEA: 26288 /// ENTRY R07770 Reaction DEFINITION ATP + (R)-Lipoate <=> Diphosphate + Lipoyl-AMP EQUATION C00002 + C16241 <=> C00013 + C16238 RCLASS RC00043 C16238_C16241 ENZYME 6.3.1.20 PATHWAY rn00785 Lipoic acid metabolism rn01100 Metabolic pathways BRITE Enzymatic reactions [BR:br08201] 6. Ligase reactions 6.3 Forming carbon-nitrogen bonds 6.3.1 Acid-D-ammonia (or amine) ligases (amide synthases) 6.3.1.20 R07770 ATP + (R)-Lipoate <=> Diphosphate + Lipoyl-AMP ORTHOLOGY K03800 lipoate---protein ligase [EC:6.3.1.20] K23756 medium-chain acyl-CoA ligase / lipoate-activating enzyme [EC:6.2.1.2] DBLINKS RHEA: 12916 /// ENTRY R09846 Reaction NAME prenylcycteine methylesterase DEFINITION Protein C-terminal S-farnesyl-L-cysteine + Methanol <=> Protein C-terminal S-farnesyl-L-cysteine methyl ester + H2O EQUATION C04506 + C00132 <=> C04748 + C00001 RCLASS RC00460 C04506_C04748 RC00461 C00132_C04748 ENZYME 3.1.1.- PATHWAY rn00900 Terpenoid backbone biosynthesis rn01110 Biosynthesis of secondary metabolites BRITE Enzymatic reactions [BR:br08201] 3. Hydrolase reactions 3.1 Acting on ester bonds 3.1.1 Carboxylic-ester hydrolases 3.1.1.- R09846 Protein C-terminal S-farnesyl-L-cysteine + Methanol <=> Protein C-terminal S-farnesyl-L-cysteine methyl ester + H2O ORTHOLOGY K15889 prenylcysteine alpha-carboxyl methylesterase [EC:3.1.1.-] DBLINKS RHEA: 48523 /// ENTRY R03673 Reaction NAME L-dopachrome delta7-delta2-isomerase DEFINITION L-Dopachrome <=> 5,6-Dihydroxyindole-2-carboxylate EQUATION C01693 <=> C04185 RCLASS RC00971 C01693_C04185 ENZYME 5.3.3.12 PATHWAY rn00350 Tyrosine metabolism rn01100 Metabolic pathways BRITE Enzymatic reactions [BR:br08201] 5. Isomerase reactions 5.3 Intramolecular oxidoreductases 5.3.3 Transposing C=C bonds 5.3.3.12 R03673 L-Dopachrome <=> 5,6-Dihydroxyindole-2-carboxylate ORTHOLOGY K01827 dopachrome tautomerase [EC:5.3.3.12] K22203 dopachrome tautomerase [EC:5.3.3.12] DBLINKS RHEA: 13044 /// ENTRY R06820 Reaction NAME UDP-L-rhamnose:flavanone-7-O-glucoside 2''-O-alpha-L-rhamnosyltransferase DEFINITION Naringenin 7-O-beta-D-glucoside + UDP-L-rhamnose <=> Naringin + UDP EQUATION C09099 + C02199 <=> C09789 + C00015 COMMENT flavanone 7-O-glucoside 2''-O-beta-L-rhamnosyltransferase RCLASS RC00005 C00015_C02199 RC00049 C09099_C09789 ENZYME 2.4.1.236 PATHWAY rn00941 Flavonoid biosynthesis rn01100 Metabolic pathways BRITE Enzymatic reactions [BR:br08201] 2. Transferase reactions 2.4 Glycosyltransferases 2.4.1 Hexosyltransferases 2.4.1.236 R06820 Naringenin 7-O-beta-D-glucoside + UDP-L-rhamnose <=> Naringin + UDP IUBMB reaction hierarchy [BR:br08202] 2. Transferase reactions 2.4.1.236 R07337 Flavanone 7-O-beta-D-glucoside <=> Flavanone 7-O-[alpha-L-rhamnosyl-(1->2)-beta-D-glucoside] R06820 Naringenin 7-O-beta-D-glucoside <=> Naringin Glycosyltransferase reactions [br08203.html] Other reactions R06820 ORTHOLOGY K13080 flavanone 7-O-glucoside 2''-O-beta-L-rhamnosyltransferase [EC:2.4.1.236] /// ENTRY R03671 Reaction NAME D-fuconate hydro-lyase DEFINITION D-Fuconate <=> 2-Dehydro-3-deoxy-D-fuconate + H2O EQUATION C01680 <=> C06159 + C00001 RCLASS RC00543 C01680_C06159 ENZYME 4.2.1.67 BRITE Enzymatic reactions [BR:br08201] 4. Lyase reactions 4.2 Carbon-oxygen lyases 4.2.1 Hydro-lyases 4.2.1.67 R03671 D-Fuconate <=> 2-Dehydro-3-deoxy-D-fuconate + H2O DBLINKS RHEA: 12952 /// ENTRY R06822 Reaction DEFINITION Apigenin <=> Vitexin EQUATION C01477 <=> C01460 COMMENT enzyme not yet characterized RCLASS RC01587 C01460_C01477 PATHWAY rn00941 Flavonoid biosynthesis rn00944 Flavone and flavonol biosynthesis /// ENTRY C00099 Compound NAME beta-Alanine; 3-Aminopropionic acid; 3-Aminopropanoate FORMULA C3H7NO2 EXACT_MASS 89.0477 MOL_WEIGHT 89.09 REMARK Same as: D07561 REACTION R00489 R00904 R00905 R00906 R00907 R00908 R00909 R00910 R00911 R00912 R00913 R00914 R00915 R00916 R00917 R01164 R01166 R02473 R02474 R02741 R03286 R03288 R03935 R09379 R09648 R10821 PATHWAY map00240 Pyrimidine metabolism map00410 beta-Alanine metabolism map00640 Propanoate metabolism map00770 Pantothenate and CoA biosynthesis map01100 Metabolic pathways map01110 Biosynthesis of secondary metabolites map01240 Biosynthesis of cofactors map04080 Neuroactive ligand-receptor interaction map04974 Protein digestion and absorption MODULE M00046 Pyrimidine degradation, uracil => beta-alanine, thymine => 3-aminoisobutanoate M00119 Pantothenate biosynthesis, valine/L-aspartate => pantothenate M00913 Pantothenate biosynthesis, 2-oxoisovalerate/spermine => pantothenate ENZYME 1.2.1.3 1.2.1.5 1.2.1.19 1.5.1.26 2.6.1.18 2.6.1.19 2.6.1.55 2.6.1.120 2.8.3.- 3.4.13.4 3.4.13.5 3.4.13.18 3.4.13.20 3.5.1.6 3.5.1.21 3.5.1.22 3.5.1.100 3.5.3.17 4.1.1.11 4.1.1.15 6.3.2.1 6.3.2.11 6.3.2.23 6.3.2.36 6.3.2.44 BRITE Compounds with biological roles [BR:br08001] Peptides Amino acids Other amino acids C00099 beta-Alanine Amines Biogenic amines C00099 beta-Alanine DBLINKS CAS: 107-95-9 PubChem: 3399 ChEBI: 16958 KNApSAcK: C00001333 PDB-CCD: BAL J-GLOBAL: J4.070C ATOM 6 1 C1b C 25.6778 -16.8919 2 C6a C 24.4732 -16.1936 3 C1b C 26.8940 -16.1936 4 O6a O 23.2571 -16.8978 5 O6a O 24.4732 -14.7912 6 N1a N 28.1045 -16.8919 BOND 5 1 1 2 1 2 1 3 1 3 2 4 1 4 2 5 2 5 3 6 1 ///