ENTRY R03513 Reaction NAME UDP-N-acetyl-D-glucosamine:O-glycosyl-glycoprotein (N-acetyl-D-glucosamine to N-acetyl-D-galactosaminyl-R) beta-1,3-N-acetyl-D-glucosaminyltransferase DEFINITION UDP-N-acetyl-alpha-D-glucosamine + N-Acetyl-alpha-D-galactosaminyl-polypeptide <=> UDP + N-Acetyl-beta-D-glucosaminyl-(1->3)-N-acetyl-D-galactosaminyl-R EQUATION C00043 + C04387 <=> C00015 + C01306 RCLASS RC00005 C00015_C00043 RC00049 C01306_C04387 ENZYME 2.4.1.147 BRITE Enzymatic reactions [BR:br08201] 2. Transferase reactions 2.4 Glycosyltransferases 2.4.1 Hexosyltransferases 2.4.1.147 R03513 UDP-N-acetyl-alpha-D-glucosamine + N-Acetyl-alpha-D-galactosaminyl-polypeptide <=> UDP + N-Acetyl-beta-D-glucosaminyl-(1->3)-N-acetyl-D-galactosaminyl-R Glycosyltransferase reactions [br08203.html] N-Acetylglucosaminyltransferase reactions R03513 /// ENTRY R03510 Reaction NAME phylloquinone,hydrogen-donor:oxygen oxidoreductase (2,3-epoxidizing) DEFINITION Phylloquinone + Reduced acceptor + Oxygen <=> Vitamin K1 epoxide + Acceptor + H2O EQUATION C02059 + C00030 + C00007 <=> C05849 + C00028 + C00001 COMMENT see R05144 RCLASS RC01562 C02059_C05849 ENZYME 1.14.99.20 BRITE Enzymatic reactions [BR:br08201] 1. Oxidoreductase reactions 1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen 1.14.99 Miscellaneous 1.14.99.20 R03510 Phylloquinone + Reduced acceptor + Oxygen <=> Vitamin K1 epoxide + Acceptor + H2O DBLINKS RHEA: 16748 /// ENTRY R03511 Reaction NAME phylloquinone:oxidized-dithiothreitol oxidoreductase DEFINITION Phylloquinone + Oxidized dithiothreitol + H2O <=> Vitamin K1 epoxide + Dithiothreitol EQUATION C02059 + C01119 + C00001 <=> C05849 + C00265 RCLASS RC01562 C02059_C05849 ENZYME 1.17.4.4 PATHWAY rn00130 Ubiquinone and other terpenoid-quinone biosynthesis rn01100 Metabolic pathways rn01110 Biosynthesis of secondary metabolites rn01240 Biosynthesis of cofactors BRITE Enzymatic reactions [BR:br08201] 1. Oxidoreductase reactions 1.17 Acting on CH or CH2 groups 1.17.4 With a disulfide as acceptor 1.17.4.4 R03511 Phylloquinone + Oxidized dithiothreitol + H2O <=> Vitamin K1 epoxide + Dithiothreitol ORTHOLOGY K05357 vitamin-K-epoxide reductase (warfarin-sensitive) [EC:1.17.4.4] DBLINKS RHEA: 13820 /// ENTRY R06036 Reaction NAME UDP-glucose:D-fructose 2-alpha-D-glucosyltransferase DEFINITION UDP-D-glucose + D-Fructose <=> Sucrose + UDP EQUATION G10608 + C00095 <=> G00370 + G10619 REMARK Same as: R00806 ENZYME 2.4.1.13 BRITE Enzymatic reactions [BR:br08201] 2. Transferase reactions 2.4 Glycosyltransferases 2.4.1 Hexosyltransferases 2.4.1.13 R06036 UDP-D-glucose + D-Fructose <=> Sucrose + UDP IUBMB reaction hierarchy [BR:br08202] 2. Transferase reactions 2.4.1.13 R07256 NDP-glucose <=> NDP R06036 UDP-D-glucose <=> UDP Glycosyltransferase reactions [br08203.html] Glucosyltransferase reactions R06036 /// ENTRY R05417 Reaction DEFINITION Styrene + Oxygen + NADH + H+ <=> Styrene-cis-2,3-dihydrodiol + NAD+ EQUATION C07083 + C00007 + C00004 + C00080 <=> C07084 + C00003 COMMENT styrene dioxygenase RCLASS RC00001 C00003_C00004 RC00098 C07083_C07084 ENZYME 1.14.12.- PATHWAY rn00643 Styrene degradation rn01100 Metabolic pathways rn01120 Microbial metabolism in diverse environments rn01220 Degradation of aromatic compounds BRITE Enzymatic reactions [BR:br08201] 1. Oxidoreductase reactions 1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen 1.14.12 With NADH or NADPH as one donor, and incorporation of two atoms of oxygen into the other donor 1.14.12.- R05417 Styrene + Oxygen + NADH + H+ <=> Styrene-cis-2,3-dihydrodiol + NAD+ /// ENTRY R03514 Reaction NAME UDP-N-acetyl-D-glucosamine:O-oligosaccharide-glycoprotein (N-acetyl-D-glucosamine to N-acetyl-D-galactosamine of N-acetyl-beta-D-glucosaminyl-1,3-N-acetyl-D-galactosaminyl-R) beta-1,6-N-acetyl-D-glucosaminyltransferase DEFINITION UDP-N-acetyl-alpha-D-glucosamine + N-Acetyl-beta-D-glucosaminyl-(1->3)-N-acetyl-D-galactosaminyl-R <=> UDP + N-Acetyl-beta-D-glucosaminyl-(1->6)-[N-acetyl-beta-D-glucosaminyl-(1->3)]-N-acetyl-alpha-D-galactosaminyl-R EQUATION C00043 + C01306 <=> C00015 + C04917 REMARK Same as: R05915 RCLASS RC00005 C00015_C00043 RC00059 C01306_C04917 ENZYME 2.4.1.148 BRITE Enzymatic reactions [BR:br08201] 2. Transferase reactions 2.4 Glycosyltransferases 2.4.1 Hexosyltransferases 2.4.1.148 R03514 UDP-N-acetyl-alpha-D-glucosamine + N-Acetyl-beta-D-glucosaminyl-(1->3)-N-acetyl-D-galactosaminyl-R <=> UDP + N-Acetyl-beta-D-glucosaminyl-(1->6)-[N-acetyl-beta-D-glucosaminyl-(1->3)]-N-acetyl-alpha-D-galactosaminyl-R /// ENTRY R03515 Reaction NAME [3-methyl-2-oxobutanoate dehydrogenase (2-methylpropanoyl-transferring)]-phosphate phosphohydrolase DEFINITION [3-Methyl-2-oxobutanoate dehydrogenase (2-methylpropanoyl-transferring)] phosphate + H2O <=> [3-Methyl-2-oxobutanoate dehydrogenase (2-methylpropanoyl-transferring)] + Orthophosphate EQUATION C01308 + C00001 <=> C04726 + C00009 RCLASS RC00017 C01308_C04726 ENZYME 3.1.3.52 BRITE Enzymatic reactions [BR:br08201] 3. Hydrolase reactions 3.1 Acting on ester bonds 3.1.3 Phosphoric-monoester hydrolases 3.1.3.52 R03515 [3-Methyl-2-oxobutanoate dehydrogenase (2-methylpropanoyl-transferring)] phosphate + H2O <=> [3-Methyl-2-oxobutanoate dehydrogenase (2-methylpropanoyl-transferring)] + Orthophosphate DBLINKS RHEA: 77250 /// ENTRY R07534 Reaction NAME 1-hydroxy-1,2-dihydrolycopene:acceptor oxidoreductase DEFINITION Chloroxanthin <=> Demethylspheroidene EQUATION C15892 <=> C15898 COMMENT methoxyneurosporene dehydrogenase(crtD) RCLASS RC02080 C15892_C15898 ENZYME 1.3.99.27 PATHWAY rn00906 Carotenoid biosynthesis rn01100 Metabolic pathways rn01110 Biosynthesis of secondary metabolites BRITE Enzymatic reactions [BR:br08201] 1. Oxidoreductase reactions 1.3 Acting on the CH-CH group of donors 1.3.99 With unknown physiological acceptors 1.3.99.27 R07534 Chloroxanthin <=> Demethylspheroidene ORTHOLOGY K09845 1-hydroxycarotenoid 3,4-desaturase [EC:1.3.99.27] DBLINKS RHEA: 59339 /// ENTRY R07535 Reaction NAME S-adenosyl-L-methionine:demethylspheroidene O-methyltransferase DEFINITION Demethylspheroidene + S-Adenosyl-L-methionine <=> Spheroidene + S-Adenosyl-L-homocysteine EQUATION C15898 + C00019 <=> C15900 + C00021 RCLASS RC00003 C00019_C00021 RC02082 C15898_C15900 ENZYME 2.1.1.210 PATHWAY rn00906 Carotenoid biosynthesis rn01100 Metabolic pathways rn01110 Biosynthesis of secondary metabolites BRITE Enzymatic reactions [BR:br08201] 2. Transferase reactions 2.1 Transferring one-carbon groups 2.1.1 Methyltransferases 2.1.1.210 R07535 Demethylspheroidene + S-Adenosyl-L-methionine <=> Spheroidene + S-Adenosyl-L-homocysteine ORTHOLOGY K09846 demethylspheroidene O-methyltransferase [EC:2.1.1.210] REFERENCE 1 [PMID:7721699] AUTHORS Lang HP, Cogdell RJ, Takaichi S, Hunter CN. TITLE Complete DNA sequence, specific Tn5 insertion map, and gene assignment of the carotenoid biosynthesis pathway of Rhodobacter sphaeroides. JOURNAL J Bacteriol 177:2064-73 (1995) DOI:10.1128/JB.177.8.2064-2073.1995 REFERENCE 2 [PMID:12664193] AUTHORS Pinta V, Ouchane S, Picaud M, Takaichi S, Astier C, Reiss-Husson F. TITLE Characterization of unusual hydroxy- and ketocarotenoids in Rubrivivax gelatinosus: involvement of enzyme CrtF or CrtA. JOURNAL Arch Microbiol 179:354-62 (2003) DOI:10.1007/s00203-003-0538-3 DBLINKS RHEA: 30906 /// ENTRY C00099 Compound NAME beta-Alanine; 3-Aminopropionic acid; 3-Aminopropanoate FORMULA C3H7NO2 EXACT_MASS 89.0477 MOL_WEIGHT 89.09 REMARK Same as: D07561 REACTION R00489 R00904 R00905 R00906 R00907 R00908 R00909 R00910 R00911 R00912 R00913 R00914 R00915 R00916 R00917 R01164 R01166 R02473 R02474 R02741 R03286 R03288 R03935 R09379 R09648 R10821 PATHWAY map00240 Pyrimidine metabolism map00410 beta-Alanine metabolism map00640 Propanoate metabolism map00770 Pantothenate and CoA biosynthesis map01100 Metabolic pathways map01110 Biosynthesis of secondary metabolites map01240 Biosynthesis of cofactors map04080 Neuroactive ligand-receptor interaction map04974 Protein digestion and absorption MODULE M00046 Pyrimidine degradation, uracil => beta-alanine, thymine => 3-aminoisobutanoate M00119 Pantothenate biosynthesis, valine/L-aspartate => pantothenate M00913 Pantothenate biosynthesis, 2-oxoisovalerate/spermine => pantothenate ENZYME 1.2.1.3 1.2.1.5 1.2.1.19 1.5.1.26 2.6.1.18 2.6.1.19 2.6.1.55 2.6.1.120 2.8.3.- 3.4.13.4 3.4.13.5 3.4.13.18 3.4.13.20 3.5.1.6 3.5.1.21 3.5.1.22 3.5.1.100 3.5.3.17 4.1.1.11 4.1.1.15 6.3.2.1 6.3.2.11 6.3.2.23 6.3.2.36 6.3.2.44 BRITE Compounds with biological roles [BR:br08001] Peptides Amino acids Other amino acids C00099 beta-Alanine Amines Biogenic amines C00099 beta-Alanine DBLINKS CAS: 107-95-9 PubChem: 3399 ChEBI: 16958 KNApSAcK: C00001333 PDB-CCD: BAL NIKKAJI: J4.070C ATOM 6 1 C1b C 25.6778 -16.8919 2 C6a C 24.4732 -16.1936 3 C1b C 26.8940 -16.1936 4 O6a O 23.2571 -16.8978 5 O6a O 24.4732 -14.7912 6 N1a N 28.1045 -16.8919 BOND 5 1 1 2 1 2 1 3 1 3 2 4 1 4 2 5 2 5 3 6 1 ///