ENTRY R05273 Reaction NAME 4-hydroxy-3-methoxybenzoate:oxygen oxidoreductase DEFINITION Vanillate + NAD+ + H2O <=> 4-Hydroxy-3-methoxy-benzaldehyde + Oxygen + NADH + H+ EQUATION C06672 + C00003 + C00001 <=> C00755 + C00007 + C00004 + C00080 RCLASS RC00001 C00003_C00004 RC00075 C00755_C06672 ENZYME 1.2.3.9 BRITE Enzymatic reactions [BR:br08201] 1. Oxidoreductase reactions 1.2 Acting on the aldehyde or oxo group of donors 1.2.3 With oxygen as acceptor 1.2.3.9 R05273 Vanillate + NAD+ + H2O <=> 4-Hydroxy-3-methoxy-benzaldehyde + Oxygen + NADH + H+ IUBMB reaction hierarchy [BR:br08202] 1. Oxidoreductase reactions 1.2.3.9 R01489 Aromatic aldehyde <=> Aromatic acid R05273 4-Hydroxy-3-methoxy-benzaldehyde <=> Vanillate /// ENTRY R05272 Reaction NAME 4-formylbenzenesulfonate:NAD+ oxidoreductase DEFINITION 4-Sulfobenzaldehyde + NAD+ + H2O <=> 4-Sulfobenzoate + NADH + H+ EQUATION C06679 + C00003 + C00001 <=> C02236 + C00004 + C00080 RCLASS RC00001 C00003_C00004 RC00075 C02236_C06679 ENZYME 1.2.1.62 PATHWAY rn00623 Toluene degradation rn01120 Microbial metabolism in diverse environments rn01220 Degradation of aromatic compounds BRITE Enzymatic reactions [BR:br08201] 1. Oxidoreductase reactions 1.2 Acting on the aldehyde or oxo group of donors 1.2.1 With NAD+ or NADP+ as acceptor 1.2.1.62 R05272 4-Sulfobenzaldehyde + NAD+ + H2O <=> 4-Sulfobenzoate + NADH + H+ ORTHOLOGY K19630 4-formylbenzenesulfonate dehydrogenase [EC:1.2.1.62] DBLINKS RHEA: 18836 /// ENTRY R09033 Reaction NAME chlorophyllide magnesium-lyase (pheophorbide-forming) DEFINITION Chlorophyllide + 2 H+ <=> Pheophorbide a + Magnesium cation EQUATION C02139 + 2 C00080 <=> C18021 + C00305 RCLASS RC01012 C02139_C18021 ENZYME 4.99.1.10 PATHWAY rn00860 Porphyrin metabolism rn01110 Biosynthesis of secondary metabolites BRITE Enzymatic reactions [BR:br08201] 4. Lyase reactions 4.99 Other lyases 4.99.1 Sole sub-subclass for lyases that do not belong in the other subclasses 4.99.1.10 R09033 Chlorophyllide + 2 H+ <=> Pheophorbide a + Magnesium cation ORTHOLOGY K22013 magnesium dechelatase [EC:4.99.1.10] DBLINKS RHEA: 52795 /// ENTRY R09032 Reaction NAME primary fluorescent chlorophyll catabolite:ferredoxin oxidoreductase DEFINITION Primary fluorescent chlorophyll catabolite + 2 Oxidized ferredoxin <=> Red chlorophyll catabolite + 2 Reduced ferredoxin + 2 H+ EQUATION C18098 + 2 C00139 <=> C18022 + 2 C00138 + 2 C00080 RCLASS RC01474 C18022_C18098 ENZYME 1.3.7.12 PATHWAY rn00860 Porphyrin metabolism rn01110 Biosynthesis of secondary metabolites BRITE Enzymatic reactions [BR:br08201] 1. Oxidoreductase reactions 1.3 Acting on the CH-CH group of donors 1.3.7 With an iron-sulfur protein as acceptor 1.3.7.12 R09032 Primary fluorescent chlorophyll catabolite + 2 Oxidized ferredoxin <=> Red chlorophyll catabolite + 2 Reduced ferredoxin + 2 H+ ORTHOLOGY K13545 red chlorophyll catabolite reductase [EC:1.3.7.12] DBLINKS RHEA: 24755 /// ENTRY R09031 Reaction DEFINITION D-Allulose 6-phosphate <=> D-Fructose 6-phosphate EQUATION C18096 <=> C00085 COMMENT D-allulose-6-phosphate 3-epimerase ENZYME 5.1.3.- PATHWAY rn00051 Fructose and mannose metabolism rn01100 Metabolic pathways rn01120 Microbial metabolism in diverse environments BRITE Enzymatic reactions [BR:br08201] 5. Isomerase reactions 5.1 Racemases and epimerases 5.1.3 Acting on carbohydrates and derivatives 5.1.3.- R09031 D-Allulose 6-phosphate <=> D-Fructose 6-phosphate ORTHOLOGY K17195 D-allulose-6-phosphate 3-epimerase [EC:5.1.3.-] REFERENCE 1 [PMID:9401019] AUTHORS Kim C, Song S, Park C. TITLE The D-allose operon of Escherichia coli K-12. JOURNAL J Bacteriol 179:7631-7 (1997) DOI:10.1128/JB.179.24.7631-7637.1997 DBLINKS RHEA: 28429 /// ENTRY R03431 Reaction NAME 3-(3,5-diiodo-4-hydroxyphenyl)lactate:NAD+ oxidoreductase DEFINITION 3-(3,5-Diiodo-4-hydroxyphenyl)lactate + NAD+ <=> 3,5-Diiodo-4-hydroxyphenylpyruvate + NADH + H+ EQUATION C04367 + C00003 <=> C01244 + C00004 + C00080 RCLASS RC00001 C00003_C00004 RC00031 C01244_C04367 ENZYME 1.1.1.96 BRITE Enzymatic reactions [BR:br08201] 1. Oxidoreductase reactions 1.1 Acting on the CH-OH group of donors 1.1.1 With NAD+ or NADP+ as acceptor 1.1.1.96 R03431 3-(3,5-Diiodo-4-hydroxyphenyl)lactate + NAD+ <=> 3,5-Diiodo-4-hydroxyphenylpyruvate + NADH + H+ DBLINKS RHEA: 20296 /// ENTRY R09037 Reaction DEFINITION Acyl-CoA + Monolysocardiolipin <=> CoA + Cardiolipin EQUATION C00040 + C18129 <=> C00010 + C05980 RCLASS RC00004 C00010_C00040 RC00037 C05980_C18129 ENZYME 2.3.1.- PATHWAY rn00564 Glycerophospholipid metabolism BRITE Enzymatic reactions [BR:br08201] 2. Transferase reactions 2.3 Acyltransferases 2.3.1 Transferring groups other than aminoacyl groups 2.3.1.- R09037 Acyl-CoA + Monolysocardiolipin <=> CoA + Cardiolipin ORTHOLOGY K13511 monolysocardiolipin acyltransferase [EC:2.3.1.-] K13513 lysocardiolipin and lysophospholipid acyltransferase [EC:2.3.1.- 2.3.1.51] /// ENTRY R05278 Reaction DEFINITION 4-Sulfocatechol + Oxygen <=> 3-Sulfomuconate EQUATION C06674 + C00007 <=> C06675 RCLASS RC00388 C06674_C06675 ENZYME 1.13.11.- PATHWAY rn00627 Aminobenzoate degradation rn01120 Microbial metabolism in diverse environments BRITE Enzymatic reactions [BR:br08201] 1. Oxidoreductase reactions 1.13 Acting on single donors with incorporation of molecular oxygen (oxygenases) 1.13.11 With incorporation of two atoms of oxygen 1.13.11.- R05278 4-Sulfocatechol + Oxygen <=> 3-Sulfomuconate /// ENTRY R09035 Reaction NAME acyl-CoA:1-acyl-sn-glycero-3-phosphoserine O-acyltransferase DEFINITION Acyl-CoA + 1-Acyl-sn-glycero-3-phosphoserine <=> CoA + Phosphatidylserine EQUATION C00040 + C18125 <=> C00010 + C02737 RCLASS RC00004 C00010_C00040 RC00037 C02737_C18125 ENZYME 2.3.1.- PATHWAY rn00564 Glycerophospholipid metabolism BRITE Enzymatic reactions [BR:br08201] 2. Transferase reactions 2.3 Acyltransferases 2.3.1 Transferring groups other than aminoacyl groups 2.3.1.- R09035 Acyl-CoA + 1-Acyl-sn-glycero-3-phosphoserine <=> CoA + Phosphatidylserine ORTHOLOGY K13512 lysophospholipid acyltransferase [EC:2.3.1.23 2.3.1.-] K13515 lysophospholipid acyltransferase 5 [EC:2.3.1.23 2.3.1.-] K13517 lysophospholipid acyltransferase 1/2 [EC:2.3.1.51 2.3.1.-] K13519 lysophospholipid acyltransferase [EC:2.3.1.51 2.3.1.23 2.3.1.-] /// ENTRY C00099 Compound NAME beta-Alanine; 3-Aminopropionic acid; 3-Aminopropanoate FORMULA C3H7NO2 EXACT_MASS 89.0477 MOL_WEIGHT 89.09 REMARK Same as: D07561 REACTION R00489 R00904 R00905 R00906 R00907 R00908 R00909 R00910 R00911 R00912 R00913 R00914 R00915 R00916 R00917 R01164 R01166 R02473 R02474 R02741 R03286 R03288 R03935 R09379 R09648 R10821 PATHWAY map00240 Pyrimidine metabolism map00410 beta-Alanine metabolism map00640 Propanoate metabolism map00770 Pantothenate and CoA biosynthesis map01100 Metabolic pathways map01110 Biosynthesis of secondary metabolites map01240 Biosynthesis of cofactors map04080 Neuroactive ligand-receptor interaction map04974 Protein digestion and absorption MODULE M00046 Pyrimidine degradation, uracil => beta-alanine, thymine => 3-aminoisobutanoate M00119 Pantothenate biosynthesis, valine/L-aspartate => pantothenate M00913 Pantothenate biosynthesis, 2-oxoisovalerate/spermine => pantothenate ENZYME 1.2.1.3 1.2.1.5 1.2.1.19 1.5.1.26 2.6.1.18 2.6.1.19 2.6.1.55 2.6.1.120 2.8.3.- 3.4.13.4 3.4.13.5 3.4.13.18 3.4.13.20 3.5.1.6 3.5.1.21 3.5.1.22 3.5.1.100 3.5.3.17 4.1.1.11 4.1.1.15 6.3.2.1 6.3.2.11 6.3.2.23 6.3.2.36 6.3.2.44 BRITE Compounds with biological roles [BR:br08001] Peptides Amino acids Other amino acids C00099 beta-Alanine Amines Biogenic amines C00099 beta-Alanine DBLINKS CAS: 107-95-9 PubChem: 3399 ChEBI: 16958 KNApSAcK: C00001333 PDB-CCD: BAL NIKKAJI: J4.070C ATOM 6 1 C1b C 25.6778 -16.8919 2 C6a C 24.4732 -16.1936 3 C1b C 26.8940 -16.1936 4 O6a O 23.2571 -16.8978 5 O6a O 24.4732 -14.7912 6 N1a N 28.1045 -16.8919 BOND 5 1 1 2 1 2 1 3 1 3 2 4 1 4 2 5 2 5 3 6 1 ///